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Credibility ,According to the shape of steel: wire
pickling, forging pickling, steel plate pickling, strip pickling and so on.
According to the type of pickling
equipment, it can be divided into trough pickling, semi-continuous pickling,
full continuous pickling and tower pickling.
Removal methods of oxide scale on steel
pipe surface: mechanical method, chemical method and electrochemical method
Mechanical methods: polishing, rolling,
high pressure water washing, brushing, shot blasting, sand blasting, scaling,
etc.
Chemical method: The iron oxide scale is
removed by chemical reaction of acid, alkali and other chemical substances with
iron oxide scale on steel surface.
Electrochemical method: When pickling,
direct current is applied to both sides of steels immersed in acid solution
through electrodes to accelerate the removal of iron oxide scale.
At present, there are three main pickling
methods for steel steels in the world: single steel pickling method (steel
plate pickling method, Single Coil pickling method, single bundle wire pickling
method), continuous pickling method and semi-continuous pickling method.
Single-piece pickling is the most original
and simplest pickling method. It is characterized by pickling the whole coil of
wire or loosened coil without uncoiling, and then hanging in the pool for
washing. Due to the poor quality of pickling, low production efficiency,
especially the great environmental pollution, it has been vigorously
eliminated.
Continuous pickling is a high-yield,
high-quality and fast-developing pickling method. It ensures the continuous
operation of the unit by installing welding machine and looper device on the
unit. However, the unit is long, the equipment is complex and the investment is
high. There are two main forms of continuous pickling line: continuous
horizontal pickling line and continuous tower pickling line.
Semi-continuous pickling is relative to single-piece pickling and continuous pickling. Because it does not need to install welding machines (or simple welding machines such as sewing machines) and large capacity loopers, it is necessary to shut down when changing coils. This method is most suitable for production with output of 20-900,000 t/a.
With the improvement of people's living
standards and the increasing demand for the environment, new technologies and
production lines for iron oxide scale removal with high efficiency,
pollution-free and good quality are emerging.
The new technology of EPS treatment
eliminates the pickling of steel coil, eliminates the generation of waste,
recycles all the media, makes the surface of steel coil cleaner and has better
corrosion resistance.
EPS patented technology is developed on the
basis of SCS technology. Its basic principle is that EPS treatment is carried
out in a sealed space with special equipment. That is, the upper and lower
surfaces of plate and silk steel plate are sprayed by EPS working medium, i.e.
mixture of steel sand and water. Under the action of certain spraying force,
the oxide or iron oxide scales on the surface of plate are removed without any
residual oxides. It can make the surface of steel plate smooth and clean, which
is called green surface.
Pickling is the process of removing oxide
scales on the surface of steel pipes by chemical methods, so it is also called
chemical pickling.
Iron oxide scales (Fe203, Fe304, Fe0) formed on the surface of strip steel are alkaline oxides insoluble in water. When they are immersed in acid or sprayed with acid on the surface of strip steel, a series of chemical changes can take place between these alkaline oxides and acid.
Because the oxide scales on the surface of
carbon structural steel or low alloy steel have the properties of looseness,
pore and crack, and the oxide scales are straightened, stretched and rectified
together with the strip steel in the pickling machine, so that these pore
cracks are further increased and enlarged. Therefore, while the acid solution
reacts with the oxide scales chemically, it also passes through cracks and
pores. It reacts with the matrix iron of steel. That is to say, three kinds of
chemical reactions between iron oxide scale and metal iron and acid solution
were carried out at the beginning of acid pickling.
The most widely used pickling media are
hydrochloric acid and sulphuric acid, but the use of hydrochloric acid pickling
occupies a larger proportion in actual production. In terms of the
characteristics of the two media, hydrochloric acid can dissolve all iron oxide
scales without producing pickling residues. And hydrochloric acid basically
does not corrode the base metal, so after pickling, the surface of the plate is
smooth and bright.
Therefore, the hydrochloric acid pickling
method has the advantages of good product quality, high production capacity,
less loss of metals and acids, low cost and so on. In addition, the iron loss
of hydrochloric acid pickling is 20% lower than that of sulfuric acid pickling.
The iron loss of hydrochloric acid pickling is 0.4%~0.5% of that of acid
pickling strip steel and 0.6%~0.7% of that of sulfuric acid pickling strip
steel. The pickling rate of hydrochloric acid is 2 times higher than that of
sulfuric acid.
In recent years, due to the development of
recovery and treatment technology of hydrochloric acid waste acid (that is, the
development of acid regeneration technology), hydrochloric acid pickling method
has been widely used.
Source: China Stainless Steel Pipes Manufacturer - Yaang Pipe Industry Co., Limited (www.yaang.com)
Tel No:+86-18267732328 / Email:[email protected]
Address:Longwan District, Wenzhou, Zhejiang Province, China.
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